Phase Frequency Detector and Charge Pump for Low Jitter PLL Applications

In this paper a new technique is presented to improve the jitter performance of conventional phase frequency detectors by completely removing the unnecessary one-shot pulse. This technique uses a variable pulse-height circuit to control the unnecessary one-shot pulse height. In addition, a novel charge-pump circuit with perfect current-matching characteristics is used to improve the output jitter performance of conventional charge pumps. This circuit is composed of a pair of symmetrical pump circuits to obtain a good current matching. As a result, the proposed charge-pump circuit has perfect current-matching characteristics, wide output range, no glitch output current, and no jump output voltage. In order to verify such operation, circuit simulation is performed using 0.18 μm CMOS process parameters

Development and characterization of polymeric hollow fiber membrane with high CO2 separation performance

In this study, we prepared the polyimide based hollow fiber membrane with High CO2 permeance property. In other to prepare high permeable gas separation membrane, we synthesized novel polyimide material using 6FDA, Durene and PEG monomers. And then general property of the polyimide membrane is characterized using flat sheet type of membrane. The membranes were prepared under various controlled conditions such as retention time and concentration of the polymer. And then the hollow fiber membrane is also prepared and then characterized for confirmation of their potential. The Ionic liquid mainchain polymer is also developed to investigate the gas permeability and potential for utilization to coating materials of hollow fiber membrane. Polyimide with pendant ionic liquid (Im-PpC) membrane showed the high α(CO2/N2) value and the main chain polymer prepared by UV crosslinking with PEG & ILMP crosslinker also showed high α(CO2/N2). Please click Additional Files below to see the full abstract

Synthesis and characterization of PEEK containing imidazole moiety and effect of functional groups

Anion exchange membrane fuel cells (AEMFCs) are considered as one of the alternative power generation systems due to their high efficiency. Anion exchange membrane (AEM) is a key component in fuel cells for the transfer of anion which is effect to the performance of the fuel cell system. \Therefore, it needs to have high chemical, mechanical, and thermal stabilities, as well as excellent electrochemical properties. For these reasons, various types of novel polymeric materials have been developed for the anion exchange membrane fuel cells. Especially, hydrocarbon based polymer materials such as poly(arylene ether sulfone), poly(ether ether ketone)(PEEK), polybenzimidazole (PBI) have been fabricated for use as electrolytes in fuel cell systems. Also, a number of preparation methods have been developed to enhance the performance of fuel cell membranes. In this study, we modified the monomer by chemical modification reaction and we synthesized the PEEK based polymer with different amination degree. Also we compared the chemical stability of the PEEK based membrane with different functional groups such as ammonium and imidazolium. Finally, the effect of the contents of the anion exchange groups in the PEEK based polymer was evaluated in terms of morphology, water behavior, mechanical properties, chemical stability and ion conductivity. Please click Additional Files below to see the full abstract

Nonflammable Lithium Metal Full Cells with Ultra-high Energy Density Based on Coordinated Carbonate Electrolytes

Coupling thin Li metal anodes with high-capacity/high-voltage cathodes such as LiNi0.8Co0.1Mn0.1O2 (NCM811) is a promising way to increase lithium battery energy density. Yet, the realization of high-performance full cells remains a formidable challenge. Here, we demonstrate a new class of highly coordinated, nonflammable carbonate electrolytes based on lithium bis(fluorosulfonyl)imide (UFSI) in propylene carbonate/fluoroethylene carbonate mixtures. Utilizing an optimal salt concentr ation (4 M LiFSI) of the electrolyte results in a unique coordination structure of Li+-FSI-solvent cluster, which is critical for enabling the formation of stable interfaces on both the thin Li metal anode and high-voltage NCM811 cathode. Under highly demanding cell configuration and operating conditions (Li metal anode = 35 mu m, areal capacity/charge voltage of NCM811 cathode = 4.8 mAh cm(-2)/4 .6 V, and anode excess capacity [relative to the cathode] = 0.83), the Li metal-based full cell provides exceptional electrochemical performance (energy densities = 679 Wh kg(cell)(-1)/1,024 Wh L-cell(-1)) coupled with nonflammability

The effect of hidden female smoking on the relationship between smoking and cardiovascular disease

Background: Smoking is a known risk factor for cardiovascular morbidity and mortality, but several Korean studies have shown differing results on the association of current smoking status and the risk of cardiovascular disease (CVD). The aim of the present study was to investigate the association between smoking status and CVD (myocardial infarction and stroke) using national representative populationbased samples. The aim was also to investigate the effects of hidden smokers on the association between CVD and smoking.Methods: Data were acquired from 28,620 participants (12,875 men and 15,745 women), age 19 years or older, who participated in the Korea National Health and Nutrition Examination Survey (KNHANES) conducted from 2008 to 2016.Results: The multivariable logistic regression analysis showed that ex-smoking status was correlated with CVD when self-reported (odds ratio [OR]: 1.62; 95% confidence interval [CI]: 1.20–2.19) and for survey-cotinine verified-smoking status (OR: 1.57; 95% CI: 1.20–2.19). Interestingly, the present study showed current smoking was not significantly associated with CVD. For the effect of sex on smoking and CVD, self-reported and survey-cotinine-verified ex-smoking status were correlated with CVD in males (OR: 1.45; 95% CI: 1.04–2.04 and OR: 1.43; 95% CI: 1.02–2.02) and in females (OR: 2.74; 95% CI: 1.59–4.71 and OR: 2.92; 95% CI: 1.64–5.18). The ratios of cotinine-verified to self-reported smoking rates were 1.95 for women and 1.08 for men.Conclusions: In the current study, while ex-smoking status was significantly associated with CVD, current smoking status was not. Female ex-smoking status had a higher adjusted odds ratio for CVD than males compared to non-smoking status. An effect of hidden female smoking was also found on the association between smoking status and CVD in Korean adults

Effect of Total Leaf Numbers on the Growth and Fruit Quality in Muskmelon Plants Showing Leaf Yellowing Symptoms

This study was conducted to evaluate the influence of total leaf numbers on the growth, net formation of fruits, and occurrence of leaf yellowing symptoms (LYS) in muskmelon plants. The growth and development of LYS on muskmelon plants having 25, 30, and 35 fully expanded leaves on the vine were compared to those of the control plant having 20 leaves. Plant height, leaf area, root fresh weight, and root dry weight increased as the number of leaves increased. Plants with 35 leaves showed the greatest plant growth. Net photosynthetic rate was positively related to increasing leaf numbers with plants having over 25 leaves showing the greatest photosynthetic rates. On the other hand, there were no significant differences in chlorophyll content and root activity among treatments with different leaf numbers. The ratio of LYS infection was also greater in plants having 25-30 leaves, than in those having leaf numbers. Plants with different leaf numbers and LYS infection showed a variation in fruit quality, although LYS did not significantly affect fruit quality except net index. The plants having 20 leaves that showed LYS developed fruits that had significantly smaller flesh (mesocarp) thickness than, the plants having greater numbers of leaves. The higher sugar contents of fruits were found in the plants having 35 leaves whether they showed LYS (12.1°Bx) or not (12.5°Bx). Therefore, leaving more than 25 healthy leaves per plant was recommended for minimizing damage from LYS.OAIID:oai:osos.snu.ac.kr:snu2015-01/104/0000027607/11ADJUST_YN:NEMP_ID:A075898DEPT_CD:517CITE_RATE:0FILENAME:(이희주)effect_of_total_leaf_numbers_on_the_growth_and_fruit_quality_in_muskmelon_plants_showing_leaf_yell··.pdfDEPT_NM:식물생산과학부CONFIRM:

Multi-Color Luminescence Transition of Upconversion Nanocrystals via Crystal Phase Control with SiO2 for High Temperature Thermal Labels

Upconversion nanocrystals (UCNs)-embedded microarchitectures with luminescence color transition capability and enhanced luminescence intensity under extreme conditions are suitable for developing a robust labeling system in a high-temperature thermal industrial process. However, most UCNs based labeling systems are limited by the loss of luminescence owing to the destruction of the crystalline phase or by a predetermined luminescence color without color transition capability. Herein, an unusual crystal phase transition of UCNs to a hexagonal apatite phase in the presence of SiO2 nanoparticles is reported with the enhancements of 130-fold green luminescence and 52-fold luminance as compared to that of the SiO2-free counterpart. By rationally combining this strategy with an additive color mixing method using a mask-less flow lithography technique, single to multiple luminescence color transition, scalable labeling systems with hidden letters-, and multi-luminescence colored microparticles are demonstrated for a UCNs luminescence color change-based high temperature labeling system